The Unburnt Queen of the Andals, the Rhoynar, and of the First Men Queen of Meereen Khaleesi of the Great Grass Sea Breaker of Chains Mother of Dragons
Daenerys is polite and well-spoken, but filled with quiet determination. She used to be cowed by her brother's ambitions and his occasional cruel rages, but her time amongst the Dothraki has taught her pride, confidence and skills of command. She is still somewhat naive of the world due to being young and living her life as an exile (with only her petulant brother to rely on for knowledge), but she is intelligent and quick to understand now that she is free to pursue her own path.
Daenerys spent her entire life living on the sufferance of others, bouncing back and forth between one benefactor or the next (like Illyrio Mopatis) with her brother, until whatever dreams they had of supporting the exiles' claim wore off and they'd have to move on to another patron. As a result, Daenerys has never known a true home. Constantly living under her brother's domination has given Daenerys a great empathy with the downtrodden of the world. She is deeply sympathetic to those she perceives as oppressed, while at the same time, her pent-up frustration from years of being mentally and physically dominated by her petty would-be-king of a brother make Daenerys capable of being utterly ruthless against those she perceives as oppressing others. This has produced a large amount of black-white thinking in Daenerys's mind, and she can be idealistic to a fault. For example, on seeing the plight of the slaves in Slaver's Bay, Daenerys becomes determined that she must free all of the slaves in the region - with little thought devoted to the practical after-effects which will result from this. A particular example is when the Great Masters of Meereen crucified 163 children as she approached the city, in an attempt to intimidate her. After she took the city, instead of pardoning the slave-masters, she had 163 of them crucified in retribution, unconcerned about any negative political fallout which would result.
Unlike many in her House, Daenerys has thus far not exhibited the "Targaryen madness" that plagued her father (and to a lesser extent, Viserys). She can be ruthless to her perceived enemies, but while Viserys was cruel and demanding to his servants and even his benefactors, Daenerys reciprocates the loyalty of those who follow her with gratitude and compassion, especially her inner circle of friends and her dragons. On the other hand, insanity was often a late-onset condition in the Targaryens, and it remains to be seen how Daenerys's mentality develops as she matures.
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